Assuming that your tenant receives relevant benefit there is nothing to stop her applying for help by way of a CCG,but whether or not she gets a grant will depend on how she explains her need to move,state of the budget etc.You could do a letter supporting her application and saying why your organisation was able to help her with a tenancy,(urgent situation, state of her health etc.)
From what you say it does not sound like a 'compulsory exchange of tenancy', which I would take to be an entirely differant situation where there was some problem with the original property itself, for example, rather than a problem with other tenants.
If the application is turned down then you/she should go through the review process.
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